(Acridine-κN)(dimethyl sulfoxide-κS)diiodidoplatinum(II)
نویسنده
چکیده
In the title complex, [PtI(2)(C(13)H(9)N)(C(2)H(6)OS)], the Pt(II) atom is four-coordinated in an essentially square-planar environment defined by the N atom of the acridine ligand, the S atom of dimethyl sulfoxide, and two iodide ions. The dihedral angle between the nearly planar PtI(2)NS unit [maximum deviation = 0.083 (2) Å] and the acridine ligand [maximum deviation = 0.038 (6) Å] is 89.29 (7)°. In the crystal structure, the complex mol-ecules are arranged in a V-shaped packing pattern along the c axis and linked by inter-molecular C-H⋯O contacts into supra-molecular chains. There are also several inter-molecular π-π inter-actions between the six-membered rings, with a shortest ring centroid-centroid distance of 3.804 (5) Å.
منابع مشابه
trans-Bis(3-hydroxypyridine-κN)diiodidoplatinum(II) dimethyl sulfoxide disolvate
In the title compound, [PtI(2)(C(5)H(5)NO)(2)]·2(CH(3))(2)SO, the Pt(II) ion lies on an inversion center and is coordinated in a slightly distorted square-planar environment by two trans iodide ligands and two pyridine N atoms. In the crystal, complex mol-ecules and solvent dimethyl sulfoxide mol-ecules are linked by inter-molecular O-H⋯O hydrogen bonds.
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